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Resource Guide

Chemical Impact on Rubber Rollers

Roller Maintenance Guide

Chemical Impact On Rubber Rollers

When determining the proper wash for a customer to use on our rollers or when
evaluating a wash currently being used by a customer, the first place to look is at
the Material Safety Data Sheet. This will break down the major components of the
wash in the following categories:

Aliphatic Hydrocarbons
Aromatic Hydrocarbons
Chlorinated Hydrocarbons
Glycols
Alcohols

All hydrocarbons are petroleum based and nearly all hydrocarbons are VOCs
(Volatile Organic Compounds) which tend to be toxic.

Aliphatic Hydrocarbons are the least harmful to rubber. Most offset inks, mineral
spirits, naptha, etc. are aliphatic hydrocarbons. Although these are less harmful to
rubber than the other hydrocarbons, prolonged usage will cause chemical abrasion
such as shrinkage, premature hardening and ozone degredation. Therefore, as you
may surmise, printing inks, specifically high solvent based inks, cause most of the
damage to rollers. Proper cleaning with good solvents will help to reduce the
impact of the ink. Improper cleaning with bad solvents will further aggravate the
problem.

Aromatic Hydrocarbons are more harmful to rubber as these are primarily used as
quick drying cleansing chemicals. These hydrocarbons consist primarily of toluene
and xylene. These chemicals will attack the oils used to soften rubber, specifically
the DOP and vegetable oils used in todays compounds.

Chlorinated Hydrocarbons are nasty chemicals. They are excellent cleaning
solvents, but are very harsh and are likely to be completely outlawed in the very
near future. They consist primarily of methylene chloride and
1,1,1-Trichloroethylene. Any solvent that uses these should be avoided.

Glycols and Alcohols are used primarily in fountain solutions although the are found
in varying degrees in cleaning solvents. These chemicals tend to swell rubber on
impact (specifically glycols) which can cause problems for those shops that clean
on the run. (eg. web presses that clean on the fly and small sheet-fed shops) They
also tend to dry out the rubber thereby affecting the hardness of the rubber.

Recommendations:

In order for a consumer to prolong the life of their rollers it is imperative that they
be educated on what they are actually buying. The MSDS along with some
chemistry basis as outlined above, and better cleaning procedures will go a long
way to improving the life of any set of rollers. Although it is difficult for a GPR
representative to recommend one wash over another, we can go so far as to
suggest that when selecting a wash, choose one that has no chlorinated
hydrocarbons and have a higher percentage of aliphatics than aromatics. For
example, in the Varn family of chemicals we recommend Varn VWM or Ecoclean
over Varn V-120 or V-253. V-120 has approximately 70% aromatic to 30%
alphatic hydrocarbons. Ecoclean 35 has approximately 30% aromatic to 70%
aliphatic hydrocarbons. V-253 is more similar to V-120, VWM nearer to Ecoclean.
It should be noted that all reputable solvent companies have similar solvents and
therefore if a customer is using Prisco, for example, there is a Prisco product with
the characteristics outlined above.